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Fourier transform IR product study of the reaction of CFO radicals with O2 at 298 K |
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| Authors: | Sam I. Ahonkhai Andreas N llePeter Behr Horst Heydtmann |
| Affiliation: | Department of Chemistry, University of Benin, Benin-City Nigeria Deutsche Forschungsanstalt für Luft- und Raumfahrt, DFD, Postfach 1116, 82230 Oberpfaffenhofen Germany Institut für Physikalische und Theoretische Chemie, J.W. Goethe Universität Frankfurt, Marie Curie Strasse 11, 60439 Frankfurt am Main Germany |
| Abstract: | Experimental results are presented of a Fourier transform IR product study at 298 K of the reaction system CFO+O2 at oxygen pressures between 3 and 250 mbar. Pulsed photolysis of oxalyl fluoride (CFO)2 or formyl fluoride (CHFO) at 193 nm was used to produce CFO. As stable products we detected bis-fluoroformyl peroxide, carbonyl fluoride and carbon dioxide. The yields of the peroxide and of CF2O were measured as a function of [O2]/[precursor] and are discussed qualitatively. |
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