Zur regioselektiven nucleophilen Addition an 2,3-Dihydrobilatriene-abc |
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Authors: | Heinz Falk Franz Lehner Marianne Rothböck |
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Institution: | (1) Institut für Analytische, Organische und Physikalische Chemie der Johannes-Kepler-Universität, A-4040 Linz, Österreich |
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Abstract: | Donors are added regioselectively to position 10 of 2,3-dihydrobilatrienes-abc in a reversible reaction, which is complicated in case of strongly basic donors due to the easy deprotonation of the partially saturated ring. Compared to the bilatrienes-abc the addition equilibrium is retarded by about two orders of magnitude. |
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Keywords: | 2 3-Dihydrobilatrienes-abc Nucleophilic addition Regioselectivity |
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