| 昆虫信息素结构鉴定和合成的研究XXV.用三乙胺作烯铜锂试剂配位体合成棉铃虫和午毒蛾性信息素 |
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| 引用本文： | 刘玲玉,林国强,王咸庆.昆虫信息素结构鉴定和合成的研究XXV.用三乙胺作烯铜锂试剂配位体合成棉铃虫和午毒蛾性信息素[J].化学学报,1987,45(6):619-621. |
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| 作者姓名： | 刘玲玉 林国强 王咸庆 |
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| 作者单位： | 中国科学院上海有机化学研究所 |
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| 摘 要： |
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| 关 键 词： | 三乙胺P 十六碳化合物 乙烯 铜 碳烯 环氧化物 醛 昆虫激素 性信息素 十八碳化合物 |
Studies on the identification and syntheses of insect pheromones XXV.Syntheses of the sex pheromones of old world bollworm moth and gypsy moth by application of triethyl amine liganded vinyl cuprate |
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| LIU LINGYU,LIN GUOQIANG,WANG XIANQING.Studies on the identification and syntheses of insect pheromones XXV.Syntheses of the sex pheromones of old world bollworm moth and gypsy moth by application of triethyl amine liganded vinyl cuprate[J].Acta Chimica Sinica,1987,45(6):619-621. |
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| Authors: | LIU LINGYU LIN GUOQIANG WANG XIANQING |
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| Abstract: | Tri-Et amine liganded vinyl cuprate was employed in the synthesis of the major components of the sex pheromone of old world bollworm moth (Heliothis armigera), cis-7-hexadecenal (I) and cis-11-hexadecenal (II), and gypsy moth (Porthetria dispar), 7,8-epoxy-2-methyloctadecane (III), with high Z purity (99.9%). The overall yields of I and II from octyllithium and BuLi were 70% in 3 steps, and that of III from decyllithium was 60% in 2 steps. |
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| Keywords: | TRIETHYL AMINE P C16 COMPOUNDS ETHYLENE COPPER CARBENE EPOXIDE ALDEHYDES INSECT HORMONE SEX PHEROMONE C18 COMPOUNDS |
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