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Effect of SDBS on interfacial electron transfer at the liquid/liquid interface by thin layer method |
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| Authors: | Xiu Hui Liu Cun Wu Dong Kai Zhang Fu Peng Zhi Zhen Ding Xiao Quan Lu College of Chemistry & Chemical Engineering Northwest Normal University Lanzhou China |
| Affiliation: | College of Chemistry & Chemical Engineering, Northwest Normal University, Lanzhou 730070, China |
| Abstract: | The effect of an adsorbed anionic surfactant sodium dodecyl benzene sulfonate(SDBS) on electron transfer(ET) reaction between ferricyanide aqueous solution and decamethylferrocene(DMFc) located on the adjacent organic phase was investigated for the first time by thin layer method.The adsorption of SDBS at the interface resulted in a decay in the cathodic plateau current of bimolecular reaction with increasing concentrations of SDBS in aqueous phase.However,the rate constant of electron transfer(k_(et)) incr... |
| Keywords: | Anionic surfactant Liquid/liquid interface Electron transfer Thin layer method |
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