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Excitation energy transfer in the Li-Cs collision: Li*(2P)+Cs(6S)→Li(2S)+Cs*(5D)
Authors:D Veza  C Vadla  K Niemax
Institution:1. Institute für Spektrochemie und Angewandte Spektroskopie (ISAS), Bunsen-Kirchhoff Strasse 11, W-4600, Dortmund 1, Federal Republic of Germany
2. Institute of Physics of the University, Bijenicka 46, POB 304, YU-41001, Zagreb, Yugoslavia
Abstract:The measurement of the collisional cross section for the process Li*(2P)+Cs(6S)→Li(2S)+Cs*(5D) are reported. The technique of resonant Doppler-limited two-photon laser excitation with thermionic detection is applied. The population density of the Cs*5D state is probed by photoionization, and the signals of the Cs(6S)→Cs*(5D) and the Li(2S)→Li*(2P) transitions are compared. The value for cross section of 30 Å2 is measured, with an accuracy of 45%.
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