|
|||||
|
|
| 沙蚕磷草酸盐的合成与晶体结构 | |
| 引用本文： | 曾唏,张长庚,牟兰,卢玉振,周向葛,周忠远. 沙蚕磷草酸盐的合成与晶体结构[J]. 有机化学, 2000, 20(1): 102-107 |
| 作者姓名： | 曾唏 张长庚 牟兰 卢玉振 周向葛 周忠远 |
| 作者单位： | 1. 贵州大学化学系,贵阳550025 2. 中国科学院成都有机化学研究所,成都610041 |
| 基金项目： | 贵州省自然科学基金资助课题(编号96-3051)。 |
| 摘 要： | 合成了一种新的有机磷杀虫剂沙蚕磷[O,O,O',O'-四甲基－S,S'-(2-N,N-二甲氨基-1,3-亚丙基)-双-二硫代磷酸酯]，并制备了它的草酸盐。测定了沙蚕磷草酸盐的晶体结构，结果表明，该晶体属三斜晶系，P1空间群，晶胞参数为:a=0.74342(5)nm,b=1.1057(4)nm,c=1.45295(11)nm,α=98.018(11)°,β=101.012(4)°,γ=96.224(10)°,Z=2。通过元素分析，MS、IR及^1H,^1^3CNMR表征了该化合物的结构。 |
| 关 键 词： | 沙蚕磷草酸盐 晶体结构 有机磷化合物 杀虫剂 元素分析 红外分光光度法 质子磁共振谱法 碳13核磁共振谱法 |
| 修稿时间： | 1998-11-19 |
Synthesis and crystal stucture of shacanlin oxalate |
|
| ZENG Xi,ZHANG Chang-Geng,MOU Lan,LU Yu-Zhen,ZHOU Xiang-Ge,ZHOU Zhong-Yuan. Synthesis and crystal stucture of shacanlin oxalate[J]. Chinese Journal of Organic Chemistry, 2000, 20(1): 102-107 | |
| Authors: | ZENG Xi ZHANG Chang-Geng MOU Lan LU Yu-Zhen ZHOU Xiang-Ge ZHOU Zhong-Yuan |
| Affiliation: | ZENG Xi,ZHANG Chang- Coeng,MOU Lan,LU Yu- Zhen(Department of Chenistry, Guizhou University, 550025 Guiyang)ZHOU Xiang- Ge,ZHOU Zhong- Yuan(Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, 610041 Chengdu) |
| Abstract: | A new organophosphorus insecticide Shacanlin [O,O,O' , O ' - tetramethyl - S - S' - (2 - N ,N -dimethylamino- trimethylene) - bis - phosphonodithionate] was synthesized and its oxalate was prepared. The crystal structure of Shacanlin oxalate was determined by XRD. The x-ray single crystal structure analysis shows that the crystal is in triclinic space group P1 and the unit cell parameters as follows : a = 0.74342(5) nm , b = 1 . 1 0 5 7 ( 4 ) nm , c = 1.45295(11) nm, a = 98.018(11), B= 101.012(4), r = 96.224(10), Z = 2. The compound was characterized by elementary analyses, MS JR and 1H,13C NMR. |
| Keywords: | 0 0 0' 0' - tetramethyl -S S'-(2-N N- dimethylamino - trimethylene) - bis - phospho-nodithioate oxalate synthesis crystal structure characterization |
| 本文献已被 CNKI 万方数据 等数据库收录！ | |
| 点击此处可从《有机化学》浏览原始摘要信息 | |
| 点击此处可从《有机化学》下载全文 | |