Molecular structure of (diethyldithiocarbomoyl)diphenylthiophosphinate |
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| Authors: | V A Al'fonsov I A Litvinov O N Kataeva D A Pudovik S A Katsyuba |
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| Institution: | (1) A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan' Scientific Center of the Russian Academy of Sciences, 8 ul. Akad. Arbuzova, 420083 Kazan', Russian Federation |
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| Abstract: | X-Ray study of (diethyldithiocarbomoyl)diphenylthiophosphinate was carried out. AZ-conformation of the diethyldithiocarbomoyl ligand, which results in a short nonvalent intramolecular P...S contact (3.315 Å), is realized in the molecule. Steric hindrances in the molecule increase the P-S-C bond angle to 106.39°.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 1978–1980, October, 1995.The work was financially supported by the International Science Foundation (Gram RH1 000). |
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| Keywords: | dithiophosphonic acid dithiocarbamates mixed anhydrides nonvalent interactions X-ray analysis conformational analysis |
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