The ability of capping phenylphosphinidene ligands to confer the trigonal prismatic geometry on hexaruthenium frameworks |
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| Affiliation: | 1. IfADo – Leibniz Research Centre for Working Environment and Human Factors, Dortmund, Germany;2. ALA – Institute for Working, Learning and Aging, Bochum, Germany;1. Department of Chemistry, Inorganic Section, Jadavpur University, Kolkata 700032, India;2. Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Strasse, D-35032 Marburg, Germany |
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| Abstract: | ![]()
Reaction of [Ru3(CO)12] with a three-fold molar amount of PPhH2 in toluene under reflux affords a range of products including two hexaruthenium species, [Ru6(μ4-PPh)2(μ3-PPh)2(CO)12] and [Ru6(μ4-PPh)3(μ3-PPh)2(CO)12], established X-ray crystallographically to have distorted trigonal prismatic skeletal geometries. |
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