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Viscosities and intradiffusion coefficients in the ternary system NaCl−MgCl2−H2O at 25°C
Authors:R Mills  A J Easteal  L A Woolf
Institution:(1) Atomic and Molecular Physics Laboratories, Research School of Physical Sciences, Australian National University, Canberra, A.C.T., Australia;(2) Department of Chemistry, University of Auckland, Auckland, New Zealand
Abstract:The intradiffusion coefficients of Na+, Cl ions and water and the tracerdiffusion coefficients of Ca2+ ion have been measured in the ternary system NaCl–MgCl2–H2O at 25°C. The intradiffusion coefficients of Mg2+ in this system have been estimated from the corresponding Ca2+ diffusion measurements. Viscosities were measured at the same solution concentrations as were used for the diffusion experiments. Intradiffusion and tracerdiffusion coefficients in a range of temperatures from 5 to 45°C are reported for standard sea-water which is a member of the above ternary set.
Keywords:Ternary electrolytes  NaCl–  MgCl2  H2O  intradiffusion coefficients  viscosities  sea-water
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