Anodic perfluoroalkylation of the enol acetate of ethyl acetoacetate |
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| Authors: | V. P. Kislyi M. A. Kurykin V. A. Grinberg N. D. Kagramanov V. V. Semenov |
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| Affiliation: | (1) N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 117913 Moscow, Russian Federation;(2) A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 117813 Moscow, Russian Federation;(3) A. N. Frumkin Institute of Electrochemistry, Russian Academy of Sciences, 31 Leninsky prosp., 117071 Moscow, Russian Federation |
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| Abstract: | Electrochemical perfluoroalkylation of the enol acetate of ethyl acetoacetate was studied in the conditions of the Kolbe reaction. The yields of alkylation products depend on the competing adsorption of the enol acetate, the solvent, and perfluorocarboxylates on the surface of a platinum electrode.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 12, pp. 2948–2951, December, 1996. |
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| Keywords: | enol acetate of ethyl acetoacetate perfluoroalkyl radicals ethyl 2-perfluoroalkylacetoacetates |
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