Products of the Radiation-Chemical and Thermal Decomposition of Mercury Fulminate |
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Authors: | V P Zhulanova S I Bannov V M Pugachev S M Ryabykh |
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Institution: | (1) Kemerovo State University, ul. Krasnaya 6, Kemerovo, 650034, Russia |
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Abstract: | The products of the radiation-chemical and thermal decomposition of mercury fulminate were examined by IR spectroscopy and X-ray diffraction analysis. Upon radiolysis to 20% conversion, the fulminate ion underwent decomposition (G (decomposition) = 20 molecule/100 eV) with the formation of HgO (G = 9 ± 1 molecule/100 eV), CN– ions, and CO2. The final solid products of the radiolysis are Hg(CNH)2, a cyanide complex, the mercury carbonate oxide HgCO3 · 3HgO, the mercury cyanide oxide Hg(CN)2 · HgO, and paracyanogen (CN)n. In the thermolysis, the final solid products of decomposition are the mercury carbonate oxide HgCO3 · 2HgO, a cyanide complex, and the cluster HgnCmNoOp. |
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