The infrared and Raman spectra of solid CsSbF 5OH and CsSbF 4(OH)2 |
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| Authors: | WHJ de Beer AM Heyns |
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| Institution: | Department of Chemistry, University of South Africa, 0001 Pretoria, South Africa |
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| Abstract: | The infrared and Raman spectra of solid CsSbF 5OH and CsSbF 4(OH)2 have been studied to determine the effect of replacing one or more F--ions by OH--ions in the SbF-6-ion. The results have been obtained in the frequency ranges where the Sb-F and Sb-OH stretching modes are known to occur. The spectra are in agreement with a low site symmetry for the SbF 5OH--ion in CsSbF 5OH but are largely inconclusive as to whether the OH-groups in CsSbF 4(OH)2 have cis- or trans-symmetry. |
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