| 一维链状银配合物的合成及晶体结构 |
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| 引用本文： | 王彦,王小锋,岡村高明,徐斌,孙为银,上山寭一.一维链状银配合物的合成及晶体结构[J].无机化学学报,2006,22(8):1487-1490. |
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| 作者姓名： | 王彦 王小锋 岡村高明 徐斌 孙为银 上山寭一 |
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| 作者单位： | 1. 南京大学化学化工学院,配位化学研究所,配位化学国家重点实验室,南京,210093
2. 日本大阪大学理学研究科高分子学科,豊中市,560-0043,日本 |
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| 基金项目： | 国家高技术研究发展计划(863计划) |
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| 摘 要： | The complex Ag(L)]NO3 (1) L=1,5-bis(imidazol-1-yl)pentane] was synthesized in ethanol and water, and characterized by elemental analysis and X-ray crystal structural analysis. The result shows that the complex crystallizes in monoclinic, space group P21/c with a=0.695 7(4) nm, b=0.988 7(4) nm, c=1.974 8(7) nm, β=91.934(19)°, V=1.357 5(10) nm3, Z=4, Dcalc=1.831 g·cm-3, F(000)=752, μ=1.50 cm-1, the final R=0.036 6, wR=0.091 0. The coordination environment of Ag(Ⅰ) is nearly linear with two N atoms, and each L ligand links two Ag(Ⅰ) atoms using its two imidazolyl N atoms to generate an infinite one-dimensional (1D) chain structure. The 1D chains are further connected by C-H…O hydrogen bonds to give a three-dimensional structure. CCDC: 609514.
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| 关 键 词： | 晶体结构 银配合物 氢键 合成 |
| 文章编号： | 1001-4861(2006)08-1487-04 |
| 收稿时间： | 2006-06-01 |
| 修稿时间： | 2006-06-29 |
Synthesis and Crystal Structure of Ag(Ⅰ) Complex with One-dimensional Chain Structure |
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| WANG Yan,WANG Xiao-Feng,OKAMURA Taka-aki,XU Bin,SUN Wei-Yin and UEYAMA Norikazu.Synthesis and Crystal Structure of Ag(Ⅰ) Complex with One-dimensional Chain Structure[J].Chinese Journal of Inorganic Chemistry,2006,22(8):1487-1490. |
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| Authors: | WANG Yan WANG Xiao-Feng OKAMURA Taka-aki XU Bin SUN Wei-Yin and UEYAMA Norikazu |
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| Institution: | School of Chemistry and Chemical Engineering, Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093,School of Chemistry and Chemical Engineering, Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093,Department of Macromolecular Science, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan,School of Chemistry and Chemical Engineering, Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093,School of Chemistry and Chemical Engineering, Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093 and Department of Macromolecular Science, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan |
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| Abstract: | The complex Ag(L)]NO3 (1) L=1,5-bis(imidazol-1-yl)pentane] was synthesized in ethanol and water,and characterized by elemental analysis and X-ray crystal structural analysis. The result shows that the complex crystallizes in monoclinic, space group P21/c with a=0.695 7(4) nm, b=0.988 7(4) nm, c=1.974 8(7) nm, β=91.934(19)°,V=1.357 5(10) nm3, Z=4, Dcalc=1.831 g·cm-3, F(000)=752,μ=1.50 cm-1, the final R=0.036 6, wR=0.091 0. The coordination environment of Ag(Ⅰ) is nearly linear with two N atoms, and each L ligand links two Ag(Ⅰ) atoms using its two imidazolyl N atoms to generate an infinite one-dimensional (1D) chain structure. The 1D chains are further connected by C-H…O hydrogen bonds to give a three-dimensional structure. CCDC: 609514. |
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| Keywords: | crystal structure hydrogen bond synthesis |
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