Use of 1,10-phenanthroline in diiron dithiolate derivatives related to the [Fe-Fe] hydrogenase active site |
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| Authors: | Orain Pierre-Yves Capon Jean-François Kervarec Nelly Gloaguen Frédéric Pétillon François Pichon Roger Schollhammer Philippe Talarmin Jean |
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| Affiliation: | UMR CNRS 6521, Chimie, Electrochimie Moléculaires et Chimique Analytique, UFR Sciences et Techniques Université de Bretagne Occidentale, CS 93837, 29238 Brest-cedex 3, France. schollha@univ-brest.fr |
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| Abstract: | Treatment of [Fe(2)(micro-pdt)(CO)(6)] (pdt = S(CH(2))(3)S) with 1,10-phenanthroline (phen) in refluxing toluene affords the asymmetric complex [Fe(2)(micro-pdt)(CO)(4)(phen)] (1); the protonation of with HBF(4).OEt(2) in CD(2)Cl(2) at 203 K has been monitored by (1)H NMR. |
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