Synthesis,Characterization, and Magnetic Properties of Novel Cobalt(II) and Copper(II) Complexes with 5‐(Isonicotinamido)isophthalate Ligand |
| |
Authors: | Xiu‐Jun Deng Wen Gu Li Wang Ling‐Fei Zeng Prof. Dr. Xin Liu |
| |
Affiliation: | Department of Chemistry, Nankai University, Tianjin, 300071, P. R. China |
| |
Abstract: | Two new complexes, {[Co(INAIP) · H2O] · 2H2O}n ( 1 ), and {[Cu(INAIP)] · H2O}n ( 2 ) [H2INAIP = 5‐(isonicotinamido)isophthalic acid] were synthesized under hydrothermal conditions, and characterized by single‐crystal X‐ray structure determination, thermogravimetric analysis, X‐ray powder diffraction, and magnetic studies. In complex 1 both CoII atoms and INAIP2– ligands act as four‐connected node, whereas in 2 both CuII atoms and INAIP2– ligands act as three‐connected node. |
| |
Keywords: | Cobalt Copper 5‐(Isonicotinamido)isophthalate Magnetic properties Metal‐organic frameworks |
|
|