A Heterotetranuclear Metal Complex {Ni2Na2} with Azido Bridges |
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| Authors: | Cheng‐Min Ge Prof. Dr. Shu‐Hua Zhang Chao Feng Yin‐Guang Wang Wei Li |
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| Affiliation: | College of Chemistry and Bioengineering, Guilin University of Technology, (Key Laboratory of Nonferrous and Materials Processing Technology, Ministry of Education), Guilin 541004, P. R. China |
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| Abstract: | ![]()
The reaction of Ni(ClO4)2 · 6H2O with 3‐ethoxy‐2‐hydroxybenzaldehyde (Hemp), methylamine, and NaN3 in DMF solution, under solvothermal conditions, leads to the formation of the heterotetrametallic cluster [Ni2Na2(μ1,1,1‐N3)2(emimp)4(DMF)2] ( I ) (emimp = 2‐ethoxy‐6‐formyl‐phenolate anion, DMF = N,N‐dimethyl‐formamide). Compound I displays dominant ferromagnetic interactions through μ1,1,1‐N3 bridging mode. |
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| Keywords: | Heterotetranuclear Defective dicubane Solvothermal synthesis Magnetic properties |
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