|
|||||
|
|
Effect of conformational rigidity on the glass transition and initial decomposition temperatures of polyimides |
|
| Authors: | Ronova I A Eylshina L B Vasilyuk A N Rusanov A L Bulycheva E G |
| Institution: | (1) Russian Academy of Sciences, A. N. Nesmeyanov Institute of Organoelement Compounds, 28 ul. Vavilova, 119991 Moscow, Russian Federation |
| Abstract: | The dependence of the glass transition and initial decomposition temperatures of polyperyleneimide and polynaphthylimide on the conformational rigidity was studied by the Monte Carlo, Kuhn segment, and quantum chemical AM1 methods. The corresponding linear plots can be used for estimation of the glass transition and initial decomposition temperatures when experimental determination is difficult. |
| Keywords: | polyperyleneimides polynaphthylimides conformational analysis quantum-chemical calculations Monte Carlo method Kuhn segment glass transition temperature initial decomposition temperature |
| 本文献已被 SpringerLink 等数据库收录！ | |