Complex compounds of ferrocene in a biacceptor system |
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Authors: | Anna Jaworska-Augustyniak Jan Wojtczak |
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Institution: | (1) Photochemistry Laboratory, Department of Chemistry, A. Mickiewicz University, 60780 Pozna, Poland |
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Abstract: | Summary Three-component systems of ferrocene (FcH): carbon tetrachloride: tetranitromethane have been investigated spectrally in the 290–800 nm range. Quantitative relationships were investigated between electron-donor acceptor (EDA) complexes of ferrocene and CCl4 (FcH · CCl4) and C(NO2)4 FcH · C(NO2)4] and the ferricenium cation (FcH+) which is formed as a result of dissociation of complexes and which depends upon the initial concentration of C(NO2)4 and duration the reaction. The results prove the destabilizing influence of C(NO2)4 on the EDA complex of ferrocene and CCl4. |
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