Polarity,anisotropy of polarizability,and steric structure of two tetrahalonorcaranes |
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Authors: | Arbuzov B. A. Timosheva A. P. Vul'fson S. G. Raevskii O. A. Vereshchagin A. N. |
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Affiliation: | (1) A. E. Arbuzov Institute of Organic and Physical Chemistry, Academy of Sciences of the USSR, USSR |
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Abstract: | Conclusions On the basis of the dipole moments and Kerr constants of trans-3,4,7,7-tetrabromobicyclo[4,1,0]heptane and trans-3,4-dibromo-7,7-dichlorobicyclo[4,1,0]heptane, it was established that the most stable conformation is an anti-boat with a two-faced angle between the planes 2-3-4-5 and 5-6-1-2 of 200–215°.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2231–2234, October, 1973. |
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