| Syntheses, Characterizations, Crystal Structures and Antibacterial Activities of Two Zinc（II） Complexes with a Schiff Base Derived from o-Vanillin and p-Toluidine |
| |
| 作者姓名： | YU Yu-Yea ZHAO Guo-Liang WEN Yi-Hang |
| |
| 作者单位： | [1]Jinhua College of Profession ＆ Technology, Jinhua, Zhejiang 321017, China [2]Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua 321004, China [3]College of Chemistry and Life Sciences, Zhejiang Normal University, Jinhua 321004, China |
| |
| 摘 要： | Two new zinc（Ⅱ） complexes, [Zn2L2Ch].2[ZnL（CH3OH）Cl2] 1 and [ZnL2（NO3）2] 2, were synthesized by reacting ZnX2.nH2O （X = Cl^-, NO3^-） and a Schiff base ligand 2-[（4-methylphenylimino）methyl]-6-methoxyphenol （C15HIsNO2, L） which was obtained by the condensation of o-vanillin （2-hydroxy-3-methoxybenzaldehyde） with p-toluidine. Both 1 and 2 were characterized by single-crystal X-ray diffraction technique, elemental analysis, molar conductance, FT-IR, UV-Vis, IH-NMR spectra and thermogravimetrie analysis. The Schiff base ligand and its zinc（Ⅱ） complexes have been tested in vitro to evaluate their antibacterial activity against bacteria, viz., Escherichia Coli, Staphylococcus aureus and Bacillus Subtilis. The results show that these complexes have higher activity than the corresponding free Schiff base ligand against the same bacteria.
|
| 关 键 词： | 香草醛 P-甲苯胺 锌（Ⅱ） 络合物 晶体结构 抗菌活性 |
| 收稿时间： | 2007-01-30 |
| 修稿时间： | 2007-05-21 |
| 本文献已被 维普 等数据库收录！ |
|
