Mechanism and kinetics of the thermal decomposition of 5-aminotetrazole |
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| Authors: | A. A. Paletsky N. V. Budachev O. P. Korobeinichev |
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| Affiliation: | (1) Department of Chemical Engineering, Catalysis and Chemical Reaction Engineering Laboratories, University of Saskatchewan, 57 Campus Drive, Saskatoon, Canada, S7N 5A9 SK; |
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| Abstract: | The kinetics of 5-aminotetrazole thermal decomposition in the condensed phase at high heating rates (∼100 K/s) was studied by the dynamic mass spectrometric thermal analysis using a molecular beam sampling system, and the product composition was determined. Two routes of 5-aminotetrazole decomposition were distinguished, one yielding HN3 and NH2CN (route 1), and the other N2 and CH3N3 (route 2). The activation energy and rate constant of 5-AT decomposition were determined for each route. |
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