Crystal structure of tetrakisdiphenylammonium hexadecachlorotetrabismuthate(III) |
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| Authors: | Al-Farhan Khalid A. Al-Wassil Abdulaziz I. |
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| Affiliation: | (1) Department of Chemistry, College of Science, King Saud University, 11451 Riyadh, Saudi Arabia |
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| Abstract: | [(C6H5)2NH2]4+[Bi4Cl16]4– crystallizes in the triclinic space group witha=11.835(2),b=12.393(2),c=12.625(3)Å,  =108.37(3),  =108.69(3),  =96.00(3)° andDc=2.135 g cm–3 forZ=1. The [Bi4Cl16]4– anion is a centrosymmetric cluster of four distorted edge-sharing BiCl6 octahedra. The ranges of the Bi–Cl bonds are 2.484(4)–2.606(3)Å for Bi–Cl(terminal), 2.691(3)–2.956(4)Å for Bi-Cl(µ2), and 2.960(3)–3.120(4)Å for Bi-Cl(µ3). The cations and anions are held in place by weak hydrogen bonds. |
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| Keywords: | Crystal structure bismuth chloride complexes diphenylammonium |
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