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| Synthesis and Crystal Structure of a Novel Binuclear Cu（ Ⅱ ） Complex with Tetradentate Schiff-base Ligand | |
| 作者姓名： | ZHAO Hai-Yana b QIU Xiao-Hanga① TONG Xiao-Lana SHEN Pan-Wena a (Department of Chemistry Nankai University Tianjin 300071 China) b (College of Science Hebei University of Science and Technology Shijiazhuang 050018 China) |
| 作者单位： | ZHAO Hai-Yana，b QIU Xiao-Hanga① TONG Xiao-Lana SHEN Pan-Wena a (Department of Chemistry，Nankai University，Tianjin 300071，China) b (College of Science，Hebei University of Science and Technology，Shijiazhuang 050018，China) |
| 摘 要： | 1 INTRODUCTION Many metalloenzymes containing in their active sites two copper ions that operate cooperatively occur in plants and animals. They are utilized for dioxygen transport or activation, electron transfer, reduction of nitrogen oxides, and hydrolytic che- mistry[1]. Consequently binuclear copper complexes with two ions in close proximity have received a great deal of attention[2～4]. These complexes are particularly of interest in the field of biomimetic chemistry to provide impr… |
| 关 键 词： | Schiff base copper （Ⅱ） complex crystal structure hydrogen bonds |
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