2′-(2-噻吩亚甲基)-2-羟基苯甲酰腙钴(Ⅲ)配合物的合成、表征及晶体结构 |
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引用本文: | 杨健国,潘富友,贾文平,李 芳.2′-(2-噻吩亚甲基)-2-羟基苯甲酰腙钴(Ⅲ)配合物的合成、表征及晶体结构[J].无机化学学报,2009,25(12):2207-2210. |
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作者姓名: | 杨健国 潘富友 贾文平 李 芳 |
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作者单位: | 1. 台州学院设备管理处,台州,317000 2. 台州学院医药化工学院,台州,317000 |
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基金项目: | 浙江省自然科学基金资助项目 |
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摘 要: | In ethanol, a mononuclear cobalt(Ⅱ) complex incorporating 2′-(2-Thienylidene)-2-Hydroxybenzoylhydra-zide has been synthesized and characterized by IR, UV-Vis, elemental analysis and X-ray crystal structure analysis. The crystal belongs to triclinic system, space group P1 with cell constant, a=1.230 69(10) nm, b=1.329 18(11) nm, c=1.330 56(11) nm, α=113.702(2)°, β=91.590(2)°, γ=100.846(2)°, V=1.944 4(3) nm3, Z=2, μ=0.662 mm-1, Dc=1.482 g·cm-3, F(000)=896, Rint=0.048 7. The crystal structure shows an anionic didentate ligand O and N donors in this work. The cobalt(Ⅲ) atom is hexacoordinated with oxygen atom from keto group and nitrogen atom from amide to form a cobalt atom for the core octahedral structure. CCDC: 748882.
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关 键 词: | 钴配合物 2′-(2-噻吩亚甲基)-2-羟基苯甲酰腙 晶体结构 合成 |
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