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Quenching of Flame Propagation Through Endothermic Reaction
Authors:Peter L. Simon  Serafim Kalliadasis  John H. Merkin  Stephen K. Scott
Abstract:
The propagation of a premixed laminar flame supported by an exothermic chemical reaction under adiabatic conditions but subject to inhibition through a parallel endothermic chemical process is considered. The temperature dependence of the reaction rates is assumed to have a generalised Arrhenius type form with an ignition temperature, below which there is no reaction. The heat loss through the endothermic reaction, represented by the dimensionless parameter agr, has a strong quenching effect on wave initiation and propagation. The temperature profile can have a front or a pulse structure depending on the relative value of the ignition temperatures and on the value of the parameters agr and beta, the latter represents the rate at which inhibitor is consumed relative to the consumption of fuel. The wave speed-cooling parameter (agr) curves are determined for various values of the other parameters. These curves can have three different shapes: monotone decreasing, sup-shaped or S-shaped, with the possibility of having one, two or three different flame velocities for the same value of the cooling parameter agr.
Keywords:laminar flame  step function  travelling wave
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