| Synthesis and Crystal Structure of 1,2-Dis（1,3-diphenylpropan-2-yl）disulfane |
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| 引用本文： | 冯附,黄猛,王乾有,段正超,涂海洋,张爱东,胡卫兵.Synthesis and Crystal Structure of 1,2-Dis（1,3-diphenylpropan-2-yl）disulfane[J].结构化学,2013(9):1275-1278. |
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| 作者姓名： | 冯附 黄猛 王乾有 段正超 涂海洋 张爱东 胡卫兵 |
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| 作者单位： | School of Chemistry and Environmental Engineering,Hubei Institute for Nationalities;Key Laboratory of Pesticide and Chemical Biology of Ministry of Education,College of Chemistry, Central China Normal University; |
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| 基金项目： | Supported by the Natural Science Foundation of Hubei Province（No.2012FFB01103）; the Hubei Provincial Department of Education（No.Q20131905）; the National Natural Science Foundation of China（No.21262011）; the Fund of Ethnic Affairs Commission of China（No.12HBZ010）; the Team Research for Excellent Mid-aged and Young Teachers of Higher Education of Hubei Province（T201006） |
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| 摘 要： | A novel compound of 1,2-dis(1,3-diphenylpropan-2-yl)disulfane(C30H30S2,Mr=454.27)was synthesized in ethanol with 1,3-diphenyl-2-propanone as raw materials,giving high yield of product(90%).Its structure was determined by IR,1H NMR,MS,elemental analysis and X-ray diffraction.The crystal belongs to monoclinic,space group C2 with a=18.727(3),b=6.5179(9),c=13.7576(18),β=131.0610(10)o,V=1266.2(3)3,Z=2,Dc=2.136 g/cm3,μ=1.078 mm-1,F(000)=843,R=0.0490 and wR=0.1247 for 3211 observed reflections with I>2(I).X-ray analysis reveals that the molecule is not symmetrical.There exist no classical hydrogen bonds andπ-πstacking interactions.Moreover,the thermal stability of compound 3 was investigated.
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| 关 键 词： | 1 3-diphenyl-2-propanone synthesis crystal structure |
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