Electrophilic isomerization of fluoroaliphatic oxygen-containing compounds |
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| Authors: | S D Chepik V F Cherstkov E I Mysov A F Aérov M V Galakhov S R Sterlin L S German |
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| Institution: | (1) A. N. Nesmeyanov Institute of Organometallic Compounds, Academy of Sciences of the USSR, Moscow |
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| Abstract: | An unusual electrophilic cyclization of fluorine-containing carbonyl compounds and  -oxides was discovered. Upon the action of SbF5, perfluorinated ketones, diketones, and -oxides isomerize to oxolanes. This reaction proceeds with the obligatory participation of the terminal CF3 group.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2611–2618, November, 1991. |
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