| Abstract: | Despite efforts by the membrane community to develop polymeric materials with improved O2/N2 separation performance, limited progress has occurred for almost a decade. Molecular sieving media, which can exhibit gas separation properties superior to polymers, tend to be brittle and uneconomical to produce for large‐scale membrane separation processes. Considering this, the polymer structures investigated in this work were designed to mimic aspects of the structure of molecular sieving media such as zeolites and carbon molecular sieves while maintaining the processability associated with polymers. Significantly attractive gas separation material properties were obtained using hyper rigid polypyrrolone copolymers with controlled packing disruptions between flat, packable segments. The gas transport properties in the materials changed dramatically as a result of different average interchain spacing. Moreover, all of the polypyrrolones studied in this work exhibited performance lying on or above the existing O2/N2 upper bound trade‐off line between permselectivity and permeability. These results, therefore, may point the way to a new cycle of membrane materials improvements for gas separations. © 1999 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 37: 1235–1249, 1999 |
