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[{Cp*(OC)2Re}2(μ‐POH)], ein Zweikernkomplex mit einem verbrückenden Hydroxiphosphiniden‐Liganden |
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| Authors: | Markus Ehses,Guido Schmitt,Gotthelf Wolmershä user,Otto J. Scherer |
| Abstract: | [{Cp*(OC)2Re}2(μ‐POH)], a Dinuclear Complex with a Bridging Hydroxiphosphinidene Ligand The reaction of [{Cp*(OC)2Re}4(μ4‐η1 : η1 : η1 : η1‐P2)] ( 1 ) with 0.1 m HCl gives [{Cp*(OC)2Re}2(μ‐POH)] ( 2 ), the X‐ray crystal structure of which reveals a dinuclear rhenium complex with a μ‐POH (hydroxiphosphinidene) ligand. |
| Keywords: | Rhenium Coordination compound POH ligand Crystal structure |