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N-Substituted Corroles: A Novel Class of Chiral Ligands
Authors:Zeev Gross  Nitsa Galili
Abstract:Although known for almost 35 years , N-substituted corroles have only now been recognized as being chiral. Several examples of these species were prepared in a facile two-step synthesis and separated into their enantiomers by HPLC. The zinc(II ) complex of the corrole shown schematically was also synthesized.
Keywords:Asymmetric synthesis  Chiral resolution  Corroles  Porphyrinoids
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