[Mn(en)]3[Cr(CN)6]2⋅4 H2O: A Three-Dimensional Dimetallic Ferrimagnet (Tc=69 K) with a Defective Cubane Unit |
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| Authors: | Masaaki Ohba,Naoki Usuki,Nobuo Fukita,Hisashi Ō kawa |
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| Abstract: | ![]()
The first modified analogue of the AII3[BIII(CN)6]2⋅x H2O type of Prussian-Blue, the title compound, has a three-dimensional network structure extended by CrIII-CN-MnII linkages, which is based on a defective cubane unit comprising three Cr and four Mn ions (see structure), and shows ferrimagnetic ordering below 69 K. |
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| Keywords: | Chromium Magnetic properties Manganese Network structures |
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