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BDH-TTP as a Structural Isomer of BEDT-TTF,and Its Two-Dimensional Hexafluorophosphate Salt
Authors:Jun-ichi Yamada  Maki Watanabe  Hiroyuki Anzai  Hiroyuki Nishikawa  Isao Ikemoto  Koichi Kikuchi
Abstract:
Metallic behavior down to low temperature is shown by charge transfer salts of BDH-TTP ( 1 ), a structural isomer of bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF). In the case of (BDH-TTP)2PF6 this behavior is attributed to the structure, which is made up of κ-type sheets of BDH-TTP donor molecules and sheets of PF6 anions.
Keywords:Charge transfer  Conducting materials  Lewis acids  Radical ions  Sulfur heterocycles
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