Kinetics of the geometric isomerization of aqueous cis-diamminedichloroplatinum(II) |
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| Authors: | Carolyn P Hicks and Michael Spiro |
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| Institution: | (1) Department of Chemistry, Imperial College of Science and Technology, SW7 2AY London, UK |
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| Abstract: | The rate of the isomerization of cis-diamminedichloroplatinum(II) to the trans form has been determined in aqueous KCl solutions from 65°C to 100°C. At 37°C the half-life is 1.8 years. Pt, AgCl, Si, SiO2, and graphite did not catalyse the isomerization while other chemical reactions occurred with Ag and Ketjenblack carbon.
                 -  (II)  -  KCl 65°C 100°C.  37°C 1,8  . Pt, AgCl, Si, SiO2  ,   Ag Ketjenblack.
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