Synthesis and crystal structure of 1-(aminomethyl)vinylphosphonic acid |
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| Authors: | Henryk Krawczyk ?ukasz Albrecht Wojciech M. Wolf |
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| Affiliation: | a Institute of Organic Chemistry, Technical University (Politechnika), 90-924 ?ód?, ?eromskiego 116, Poland
b Institute of General and Ecological Chemistry, Technical University (Politechnika), 90-924 ?ód?, ?eromskiego 116, Poland |
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| Abstract: | A highly efficient and versatile approach to the synthesis of 1-(aminomethyl)vinylphosphonic acid, a constituent of the antibiotic A53868A, is reported. In the crystal, molecules of the acid are linked by strong, linear, symmetric hydrogen bonds involving hydrogen atoms of the phosphonic group. |
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| Keywords: | Knoevenagel reaction Aminophosphonic acids Symmetric hydrogen bonds Natural bond orbitals |
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