Crystal structure of [Cu(en)2](ReO4)2 |
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| Authors: | E A Shusharina S P Khranenko and S A Gromilov |
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| Institution: | (1) Department of Inorganic Chemistry, Institute of Chemistry, P.J. Šaf?rik University, Moyzesova 11, 04154 Košice, Slovakia;(2) Institute of Inorganic Chemistry, Martin-Luther-University, Halle-Wittenberg, Kurt-Mothes-Str. 2, 06120 Halle, Germany;(3) Department of Chemistry, Juniata College, 1700 Moore St., Huntingdon, PA 16652, USA |
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| Abstract: | At T = 150 K the crystal structure of Cu(en)2] (ReO4)2 (en is ethylenediamine) is studied: a = 6.6229(1) ?, b = 14.2968(3) ?, c = 7.4859(2) ?, β = 102.415(1)°, V = 692.24(3) ?,3, P21/c space group, Z = 2, d
x
= 3.282 g/cm3. Packing of complex cations is shown to be single layered and pseudohexagonal. Perrhenate anions are located between these
layers and additionally coordinate copper atoms with Cu...O distances being 2.504(3) ?. |
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