Photochemistry of planar four-co-ordinate palladium(II) complexes—III. Photosynthesis and crystal structure of [Pd2(PPr3n2(NCS)(SCN)2(μ-CN)] |
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| Authors: | G. Bombieri G. Bruno M. Cusumano G. Guglielmo V. Ricevuto |
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| Affiliation: | Dipartimento di Chimica Inorganica e Struttura Molecolare, University of Messina, Via dei Verdi, 98100 Messina, Italy |
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| Abstract: | ![]()
U.V. irradiation of MeOH and CH3CN solutions of trans-[Pd(PPr3n)2(NCS)2] causes a stepwise photochemical reaction. When the solvent is CH3CN the photoproduct can be conveniently isolated in a crystalline form. This compound has been shown, by X-ray analysis, to be a cyano bridged palladium(II) complex. |
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| Keywords: | Author to whom correspondence should be addressed. |
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