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Reaction of furan compounds with hydrogen peroxide in the presence of vanadium catalysts
Authors:V. V. Poskonin  L. A. Badovskaya
Affiliation:(1) Krasnodar Polytechnic Institute, Krasnodar
Abstract:The reactions of furan and a number of its derivatives (furfural, furan-2-carboxylic acid, 2-furfuryl alcohol, and others), in systems containing H2O2 and vanadium compounds, proceed through a mechanism of radical hydoxylation of the furan ring with the formation of 5-hydroxy-2(5H)-furanone and maleic acid. The total yield and ratio of the synthesized compounds depend on the reaction conditions.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 11, pp. 1462–1467, November, 1991.
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