| 甲基三氧化铼(Ⅶ)席夫碱配合物的合成与晶体结构 |
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| 引用本文： | 高 宇,张月成,赵继全. 甲基三氧化铼(Ⅶ)席夫碱配合物的合成与晶体结构[J]. 无机化学学报, 2009, 25(9): 1686-1689 |
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| 作者姓名： | 高 宇 张月成 赵继全 |
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| 作者单位： | 河北工业大学化工学院,天津,300130 |
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| 基金项目： | 国家自然科学基金资助项目 |
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| 摘 要： | A novel methyltrioxorhenium(Ⅶ) (MTO) complex was synthesized by the reaction of MTO with Schiff-base ligand obtained by the condensation of 2-pyridinecarboxaldehyde with 4-bromoaniline in methanol. The complex was characterized by NMR, IR, MS, elemental analysis and X-ray diffraction single crystal structure analysis. The results showed that the crystal belongs to monoclinic, space group P21/n with a=0.965 70(19) nm, b=1.410 6(3) nm, c=1.080 4(2) nm, β=109.20(3)°, V=1.390 0(5) nm3, Mr=510.36, Z=4, Dc=2.439 g·cm-3, F(000)=952 and final R1=0.034 4, wR2=0.076 1. The crystal structure indicates that the Re(Ⅶ) atom is coordinated with both nitrogen atoms from the Schiff-base. CCDC: 740159.
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| 关 键 词： | 甲基三氧化铼(Ⅶ)配合物； 席夫碱； 晶体结构 |
Synthesis and Crystal Structure of MTO Schiff-Base Complex |
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| GAO Yu,ZHANG Yue-Cheng and ZHAO Ji-Quan. Synthesis and Crystal Structure of MTO Schiff-Base Complex[J]. Chinese Journal of Inorganic Chemistry, 2009, 25(9): 1686-1689 |
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| Authors: | GAO Yu ZHANG Yue-Cheng ZHAO Ji-Quan |
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| Affiliation: | School of Chemical Engineering, Hebei University of Technology, Tianjin 300130,School of Chemical Engineering, Hebei University of Technology, Tianjin 300130 and School of Chemical Engineering, Hebei University of Technology, Tianjin 300130 |
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