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| Synthesis and Characterization of 2,6-Bis(imino)phenoxy Cobalt Complexes | |
| 引用本文： | 韩玲芹,孙文华,王乐勇,邵长星,王宏根,李记太. Synthesis and Characterization of 2,6-Bis(imino)phenoxy Cobalt Complexes[J]. 中国化学, 2002, 20(12): 1523-1528. DOI: 10.1002/cjoc.20020201212 |
| 作者姓名： | 韩玲芹 孙文华 王乐勇 邵长星 王宏根 李记太 |
| 作者单位： | HAN，Ling-Qin a，b SUN，Wen-Hua，a WANG，Le-Yong a SHAO，Chang-Xing a WANG，Hong-Gen c LI，Ji-Tai b aState Key Laboratory of Engineering Plastics and The Center for Molecular Sciences，Institute of Chemistry，Chinese Academy of Sciences，Beijing 100080，China bDepartment of Chemistry，Hebei University，Baoding，Hebei 071002，China cState Key Laboratory of Functional Polymer，Nankai University，Tianjin 300071，China |
| 基金项目： | “OnehundredTalents”andCoreResearchforEngineeringInnovationKGCX2 0 3 2 |
| 摘 要： | ＩｎｔｒｏｄｕｃｔｉｏｎＲｅｃｅｎｔｒｅｓｅａｒｃｈｅｆｆｏｒｔｓｈａｖｅｂｅｅｎｄｅｖｏｔｅｄｔｏｔｈｅｓｔｕｄｙｏｆｌａｔｅｔｒａｎｓｉｔｉｏｎｍｅｔａｌｃｏｍｐｌｅｘｅｓａｓｍｏｄｅｌｓｙｓｔｅｍｓｆｏｒｔｈｅｐｏｌｙｍｅｒｉｚａｔｉｏｎｏｒｏｌｉｇｏｍｅｒｉｚａｔｉｏｎｏｆｅｔｈｙｌｅｎｅ .1 3ＴｈｅｍｏｓｔｎｏｔａｂｌｅａｃｈｉｅｖｅｍｅｎｔｓｈａｖｅｂｅｅｎｄｏｎｅｂｙＢｒｏｏｋｈａｒｔ,4 Ｂｅｎｎｅｔｔ,5ａｎｄＧｉｂｓｏｎｇｒｏｕｐｓ .6,7Ｔｈｅｙｉｎｄｅ ｐｅｎｄｅｎｔｌｙｒｅｐｏｒ… |
Synthesis and Characterization of 2,6-Bis(imino)phenoxy Cobalt Complexes |
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| HAN,Ling-Qin a,b SUN,Wen-Hua,a WANG,Le-Yong a SHAO,Chang-Xing a WANG,Hong-Gen c LI,Ji-Tai b aState Key Laboratory of Engineering Plastics and The Center for Molecular Sciences. Synthesis and Characterization of 2,6-Bis(imino)phenoxy Cobalt Complexes[J]. Chinese Journal of Chemistry, 2002, 20(12): 1523-1528. DOI: 10.1002/cjoc.20020201212 | |
| Authors: | HAN Ling-Qin a b SUN Wen-Hua a WANG Le-Yong a SHAO Chang-Xing a WANG Hong-Gen c LI Ji-Tai b aState Key Laboratory of Engineering Plastics The Center for Molecular Sciences |
| Affiliation: | HAN,Ling-Qin a,b SUN,Wen-Hua,a WANG,Le-Yong a SHAO,Chang-Xing a WANG,Hong-Gen c LI,Ji-Tai b aState Key Laboratory of Engineering Plastics and The Center for Molecular Sciences,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100080,China bDepartment of Chemistry,Hebei University,Baoding,Hebei 071002,China cState Key Laboratory of Functional Polymer,Nankai University,Tianjin 300071,China |
| Abstract: | A series of cobalt complexes bearing 2,6-bis(imino)phenoxy ligands, LCoCl 2 [L=2,6-(ArNCH) 2~CH 3~C 6~H 2OH] was synthesized by the reaction of the ligand 2,6-bis(imino)phenol with the equivalent mole of cobalt dichloride, and these complexes were characterized by elemental analyses, 1H NMR, MS and IR spectra. The structure of one complex was determined by single crystal X-ray diffraction analysis. |
| Keywords: | cobalt complex Schiff-base crystal structure |
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