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Visible‐Light‐Mediated Chan–Lam Coupling Reactions of Aryl Boronic Acids and Aniline Derivatives
Authors:Dr Woo‐Jin Yoo  Tatsuhiro Tsukamoto  Prof Dr Shū Kobayashi
Institution:Department of Chemistry, School of Science, The University of Tokyo, Hongo, Bunkyo‐ku, Tokyo 113‐0033 (Japan)
Abstract:The copper(II)‐catalyzed aerobic oxidative coupling reaction between aryl boronic acids and aniline derivatives was found to be improved significantly under visible‐light‐mediated photoredox catalysis. The substrate scope of this oxidative Chan–Lam reaction was thus expanded to include electron‐deficient aryl boronic acids as viable starting materials.
Keywords:C  N coupling  copper catalysis  cross‐coupling  oxidation  photocatalysis
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