Visible‐Light‐Mediated Chan–Lam Coupling Reactions of Aryl Boronic Acids and Aniline Derivatives |
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Authors: | Dr Woo‐Jin Yoo Tatsuhiro Tsukamoto Prof Dr Shū Kobayashi |
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Institution: | Department of Chemistry, School of Science, The University of Tokyo, Hongo, Bunkyo‐ku, Tokyo 113‐0033 (Japan) |
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Abstract: | The copper(II)‐catalyzed aerobic oxidative coupling reaction between aryl boronic acids and aniline derivatives was found to be improved significantly under visible‐light‐mediated photoredox catalysis. The substrate scope of this oxidative Chan–Lam reaction was thus expanded to include electron‐deficient aryl boronic acids as viable starting materials. |
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Keywords: | C N coupling copper catalysis cross‐coupling oxidation photocatalysis |
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