Redox‐Active NOx Ligands in Palladium‐Mediated Processes |
| |
| Authors: | Prof Ian J S Fairlamb |
| |
| Institution: | Organic and Inorganic Chemistry, University of York, Chemistry, Heslington, York, YO10 5DD (UK) |
| |
| Abstract: | This Minireview highlights the redox and non‐innocent behavior of NOx ligands (x=1, 2, or 3) in selected Pd‐mediated processes, for example, alkene and aromatic oxidation processes. A focus is placed on mechanistic understanding and linking recent transformations, such as C? H bond activation/functionalization and Wacker oxidation, with previous work on the functionalization of aromatics and alkenes by PdII salts. |
| |
| Keywords: | C C coupling oxidation palladium reaction mechanisms redox reactions |
|
|
