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Synergistic catalysis of isolated Fe~(3+) and Fe_2O_3 on FeO_x/HZSM-5 catalysts for Friedel-Crafts benzylation of benzene |
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| Authors: | Tao Lin Xin Zhang Rong Li Ting Bai Si Ying Yang School of Chemical Engineering Northwest University Xi'an China |
| Institution: | School of Chemical Engineering, Northwest University, Xi'an 710069, China |
| Abstract: | FeO_x/HZSM-5 catalyst with 8 wt.%Fe-loading(8-FeZ) exhibited significantly higher reactivity in the benzylation of benzene with benzyl chloride than FeO_x/HZSM-5 catalyst with 2.5 wt.%Fe-loading(2.5-FeZ) because the synergistic catalysis between isolated Fe~(3+) and superfine Fe_2O_3 occurred on 8-FeZ in the reaction. |
| Keywords: | Friedel-Crafts Synergistic catalysis Benzene Diphenylmethane Fe~(3 ) FeO_x/HZSM-5 |
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