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Off-on-off luminescent switching of a dye containing imidazo[4,5-f][1,10]phenanthroline
Authors:Hai Guang Zhang  Xu Tang Taob  Kao Shan Chenc  Chun Xue Yuanb  Shi Na Yana  Min Hua Jiangb a College of Chemistry Science  Qufu Normal University  Qufu  China b State Key Laboratory of Crystal Materials  Sh  ong University  Jinan  China c School of Life Science  China
Institution:a College of Chemistry Science, Qufu Normal University, Qufu 273165, China;b State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, China;c School of Life Science, Shandong University, Jinan 250100, China
Abstract:A new acid-base fluorescent switch containing both imidazo4,5-f]1,10]-phenanthroline and triphenylamine groups has been synthesized.Its fluorescence emissions and absorptions can be reversibiy changed through protonation/deprotonation of imidazole and amine moiety by controlling the intramolecular charge transfer(ICT) process,leading to off-on-off fluorescent molecular switching.
Keywords:Fluorescence switch  Imidazo[4  5-f][1  10]phenanthroline  Triphenylamine  Intramolecular charge transfer(ICT)  
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