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The Friedel-Crafts Acylation of Substituted Benzene with 2 - Phenylfuran-3, 4-dicarboxylic Acid Anhydride
引用本文:Xiao Ping NIE and Xiu Lin YE(Department of Chemistry,Peking University,Bejing 100871). The Friedel-Crafts Acylation of Substituted Benzene with 2 - Phenylfuran-3, 4-dicarboxylic Acid Anhydride[J]. 中国化学快报, 1998, 0(2)
作者姓名:Xiao Ping NIE and Xiu Lin YE(Department of Chemistry  Peking University  Bejing 100871)
作者单位:Department of Chemistry,Peking University,Bejing 100871
摘    要:TheFriedel-Craftsacylationreactions'-2areofparticularvalueowingt0theselectivityandeasewithwhichtheyareusuallyacc0mPlished,thusprovidingusefulroutestohighlyfimctionalinedar0maticringsystems.Sincesesamin-grouPlignanshavetW0aro-maticmoieties,theaPplicationoftheFriedel-CraftsacylationreactioninourstratCgyforsynthesisofsuchlignansseemedprondsing.Hence,titlecomPoundlwaschosenastheacylatingagenttoexaminesuchfeasibility.Ourresearchw0rkwasstartedfrom2,4-diphenyloxazole2,theprepaxation0fwhichwasgrea…


The Friedel-Crafts Acylation of Substituted Benzene with 2 - Phenylfuran-3,4-dicarboxylic Acid Anhydride
Xiao Ping NIE and Xiu Lin YE. The Friedel-Crafts Acylation of Substituted Benzene with 2 - Phenylfuran-3,4-dicarboxylic Acid Anhydride[J]. Chinese Chemical Letters, 1998, 0(2)
Authors:Xiao Ping NIE and Xiu Lin YE
Abstract:2 -Phenyl furan-3,4-dicarboxylic acid anhydride reacted with seven aromatic compounds,of which five gave keto acids in yields of 94%-63%. The structure of the keto acid was elucidatedby reducing it to hydroxy acid and analyzing with NMR technique.
Keywords:Friedel-Crafts acylation   2-phenylfuran-3   4 -dicarboxylic acid anhydride   structure elucidation
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