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Relaxation studies in magnetic resonance spectroscopy
Authors:H.A. Bergen  R.M. Golding  L.C. Stubbs
Affiliation:Department of Physical Chemistry , University of New South Wales , P.O. Box 1, Kensington , N.S.W. , 2033 , Australia
Abstract:The electron spin and nuclear spin relaxation in liquid solution arising from the electron-nuclear interaction is determined for the general case when the g-tensor may be anisotropic and the nine hyperfine interaction tensor components may be all different. The theoretical expressions are used in an attempt to interpret the relaxation times T 1 and T 2 for the various nuclei in the complex ruthenium acetylacetonate.
Keywords:
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