| 酞菁键合硅胶的制备及分离取代酞菁异构体 |
| |
| 引用本文： | 方 昕,林国发,许秀枝,王俊东,陈耐生.酞菁键合硅胶的制备及分离取代酞菁异构体[J].无机化学学报,2007,23(11):1935-1940. |
| |
| 作者姓名： | 方 昕 林国发 许秀枝 王俊东 陈耐生 |
| |
| 作者单位： | 福州大学化学化工学院功能材料研究所,结构化学国家重点实验室,福州,350002 |
| |
| 摘 要： | 制备和表征了一种新的酞菁键合硅胶，三-β-(辛巯基)-β-(磺酰胺基)-酞菁铜键合硅胶。研究了该键合酞菁硅胶作为HPLC固定相的基本色谱性能。实验结果表明，该固定相可以分离四-α-(2，2，4-三甲基-3-戊氧基)酞菁(铜、镍)的4种异构体，也可以观察到四-α-(2，2，4-三甲基-3-戊氧基)无金属酞菁的4种异构体，而商业C18(VERTEX Eurospher)却只能观察到两组峰，表明这种酞菁键合硅胶固定相在分析、分离一些取代酞菁异构体方面比商业C18具有更好的分离效果。
|
| 关 键 词： | 酞菁键合硅胶 制备 分离 异构体 |
| 文章编号： | 1001-4861（2007）11-1935-06 |
| 修稿时间： | 2007-07-09 |
Preparation of Phthalocyanine Bonded Silica Gel for the Separation of Phthalocyanine Isomers |
| |
| FANG Xin,LIN Guo-F,XU Xiu-Zhi,WANG Jun-Dong and CHEN Nai-Sheng.Preparation of Phthalocyanine Bonded Silica Gel for the Separation of Phthalocyanine Isomers[J].Chinese Journal of Inorganic Chemistry,2007,23(11):1935-1940. |
| |
| Authors: | FANG Xin LIN Guo-F XU Xiu-Zhi WANG Jun-Dong and CHEN Nai-Sheng |
| |
| Institution: | Institute of Research on Function Materials, College of Chemistry and Chemical Engineering, Fuzhou University; State Key Laboratory of Structural Chemistry, Fuzhou 350002,Institute of Research on Function Materials, College of Chemistry and Chemical Engineering, Fuzhou University; State Key Laboratory of Structural Chemistry, Fuzhou 350002,Institute of Research on Function Materials, College of Chemistry and Chemical Engineering, Fuzhou University; State Key Laboratory of Structural Chemistry, Fuzhou 350002,Institute of Research on Function Materials, College of Chemistry and Chemical Engineering, Fuzhou University; State Key Laboratory of Structural Chemistry, Fuzhou 350002 and Institute of Research on Function Materials, College of Chemistry and Chemical Engineering, Fuzhou University; State Key Laboratory of Structural Chemistry, Fuzhou 350002 |
| |
| Abstract: | |
| |
| Keywords: | phthalocyanine bonded silica gel preparation separate isomer |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
| 点击此处可从《无机化学学报》浏览原始摘要信息 |
| 点击此处可从《无机化学学报》下载免费的PDF全文 |
|
