| Synthesis and Crystal Structure of FeCo_2(CO)_8(μ_3-S)〔P(OCH_2Ph)_3〕 |
| |
| 作者姓名： | WANG Xiao-Ling SUO Quan-Ling WANG Yi-Bing LU Qing-Wei |
| |
| 作者单位： | WANG Xiao-Ling ;SUO Quan-Ling; WANG Yi-Bing; LU Qing-Wei(Department of Chemical Engineering，Inner Mongolia Polytechnic University，Hohhot，010062)SUN Jie(Shanghai Institute of Organic Chemistry，the Chinese Academyof Sciences，Shanghai，200032) |
| |
| 摘 要： | 1INTRODUCTIONBytreatingFeCo2(CO),(p,-S)withgroupVligandsL=PPh,,AsPh,,PBus",p(OEt),j,monosubstitutedderivativesFeCo2(CO),(p,-S)(L)havebeenobtained{1'2i.13C-NMRshowedthatthereplacementofCObyagroupVligandinFeCo,(CO),(p,-S)isatonecobaltatominthemonosubstitutedderivativet2).How-ever,thesubstitutedderivativeofFeCo,(CO),(p,-S)withP(OCH,Ph),hasnotbeenreportedanditscrystalstructurehasnotbeendetermined.WehavesynthesizedthetitlecompoundFeCo,(CO),(p,-S)P(OCH,Ph),jandtestifiedth…
|
Synthesis and Crystal Structure of FeCo_2 (CO)_8 (μ_3-S)〔P(OCH_2Ph)_3〕 |
| |
| WANG Xiao-Ling ,SUO Quan-Ling, WANG Yi-Bing, LU Qing-Wei.Synthesis and Crystal Structure of FeCo_2 (CO)_8 (μ_3-S)〔P(OCH_2Ph)_3〕[J].Chinese Journal of Structural Chemistry,1998(2). |
| |
| Authors: | WANG Xiao-Ling SUO Quan-Ling WANG Yi-Bing LU Qing-Wei |
| |
| Abstract: | The title compound FeCo2 (CO)8 (μ3-S) P (OCH2Ph )3] was synthe-sized by the reaction of P (OCH2Ph)3 with FeCo2 (CO)9 (μ3-S) at room temperature.Crystal data: C29H21 O11 PSCo2Fe, Mr=782. 23, monoclinic, space group P21/n(14), a= l5. 123(4), b=14. 580(4), c=15. 942(3)A, g=115. 66(1), V=3168293K, final R= 0. 032, R= 0. 037 for 3010 observed reflections with I>3. 00(I).The monosubstituted ligand P (OCH2Ph )3 in FeCo2 (CO)8 (μ3-S ) P (OCH2Ph )3] islinked to one cobalt atom of the tetrahedron FeCo2S framework. |
| |
| Keywords: | synthesis crystal structure iron-cobalt cluster substituted reaction |
| 本文献已被 CNKI 等数据库收录！ |
|
