Accroissement de la reactivite des phosphorines en tant que dienes et philodienes par complexation du phosphore |
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| Authors: | Jean-Marie Alcaraz François Mathey |
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| Affiliation: | Laboratoire CNRS-SNPE, 2–8 rue Henry Dunant, 94320 Thiais France |
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| Abstract: | The 2-Phenyl-4,5-dimethylphosphorin P-W(CO)5 complex reacts easily as a dienophile with 2,3-dimethylbutadiene through its 1,6-positions and as a diene with N-phenylmaleimide, dimethyl acetylenedicarboxylate and cyclopentadiene, through its 1,4-positions. |
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