Benzyne-induced ring opening reaction of thiiranes. Efficient synthesis of phenyl vinyl sulfides |
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| Authors: | Juzo Nakayama Satoshi Takeue Masamatsu Hoshino |
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| Affiliation: | Department of Chemistry, Faculty of Science, Saitama University, Urawa, Saitama 338, Japan |
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| Abstract: | A series of thiiranes react with benzyne to provide an efficient synthesis of phenyl vinyl sulfides. The reaction is stereospecific, thus producing cis-(phenylthio)-stilbene from cis-2,3-diphenylthiirane and trans-(phenylthio)stilbene from trans-2,3-diphenylthiirane. |
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