Electronic control of stereoselectivity. 20. Crystal and molecular structure of the ferrocene derived from tricyclo[5.2.1.02,6]Deca-2,5,8-triene |
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Authors: | Leh-Yeh Hsu Susan J Hathaway Leo A Paquette |
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Institution: | Evans Chemical Laboratories, The Ohio State University, Columbus, Ohio 43210 U.S.A. |
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Abstract: | Reaction of the isodicyclopentadienide anion and its dehydro congener with Fe(II) leads to a stereochemically homogeneous ferrocene derivative in each instance. Through chemical correlation and X-ray analysis, above-plane complexation is established for both halves within the two sandwich compounds. |
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Keywords: | Author to whom inquiries concerning the X-ray crystal structure analysis should be directed |
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