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Electronic control of stereoselectivity. 20. Crystal and molecular structure of the ferrocene derived from tricyclo[5.2.1.02,6]Deca-2,5,8-triene
Authors:Leh-Yeh Hsu  Susan J Hathaway  Leo A Paquette
Institution:Evans Chemical Laboratories, The Ohio State University, Columbus, Ohio 43210 U.S.A.
Abstract:Reaction of the isodicyclopentadienide anion and its dehydro congener with Fe(II) leads to a stereochemically homogeneous ferrocene derivative in each instance. Through chemical correlation and X-ray analysis, above-plane complexation is established for both halves within the two sandwich compounds.
Keywords:Author to whom inquiries concerning the X-ray crystal structure analysis should be directed  
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